Session.trust_env = False turns off the checking of environment variables for options including proxy settings (*_proxy). But urllib picks up and uses these environment proxy settings anyway. requests should pass the trust_env setting on to urllib. (Although I'm not sure if urllib has a similar override.)
(Proxy setting precedence should be sorted out here as well. They way it is now, environment proxy settings will interfere with (rather than be over-ridden by) the proxies argument in Session.request or requests.request calls and the Session.proxies config regardless of trust_env settings.)
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