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Methitural - Wikipedia

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Chemical compound

Pharmaceutical compound

Methitural ATC code IUPAC name CAS Number PubChem CID ChemSpider UNII ChEMBL CompTox Dashboard (EPA) Formula C12H20N2O2S2 Molar mass 288.42 g·mol−1 3D model (JSmol) SMILES InChI

Methitural (INN; Neraval, Thiogenal), or methitural sodium, also known as methioturiate, is a barbiturate derivative which was marketed in the 1950s in Europe (in Germany and Italy) as an ultra-short-acting intravenous anesthetic.[1][2][3]

Methitural synthesis: Zima, Von Werder, U.S. patent 2,802,827 (1957 to E. Merck).

A somewhat more complex side chain is incorporated by alkylation of the carbanion of the substituted cyanoacetate (1) with 2-chloroethylmethyl sulfide (2). Condensation of the resulting cyanoester (3) with thiourea followed by hydrolysis of the resulting imine affords methitural.

GABAA receptor positive modulators Alcohols Barbiturates Benzodiazepines Carbamates Flavonoids Imidazoles Kava constituents Monoureides Neuroactive steroids Nonbenzodiazepines Phenols Piperidinediones Pyrazolopyridines Quinazolinones Volatiles/gases Others/unsorted See also: Receptor/signaling modulatorsGABA receptor modulatorsGABA metabolism/transport modulators

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