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Bromosyl trifluoride - Wikipedia
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Chemical compound
Bromosyl trifluoride is an inorganic compound of bromine, fluorine, and oxygen with the chemical formula BrOF3.[1][2]
- Synthesis of bromosyl trifluoride is by reaction of anhydrous HF with K+[BrOF4]− (potassium tetrafluorooxobromate(V)) at –78 °C.[3]
-
-
HF + K[BrOF4] → BrOF3 + K[HF2]
Physical properties[edit]
Bromosyl trifluoride forms a colorless liquid at room temperature. It reacts with water.[5]
Chemical properties[edit]
Bromosyl trifluoride is quite unstable and decomposes at room temperature:
-
2 BrOF3 → 2 BrF3 + O2
- ^ Gillespie, Ronald J.; Spekkens, Paul H. (1 January 1977). "Bromyl fluoride and bromosyl trifluoride: preparation and chemical and spectroscopic properties". Journal of the Chemical Society, Dalton Transactions (16): 1539–1546. doi:10.1039/DT9770001539. ISSN 1364-5447. Retrieved 24 May 2023.
- ^ "bromine trifluoride oxide". ChemSrc. Retrieved 24 May 2023.
- ^ Wiberg, Egon; Wiberg, Nils (2001). Inorganic Chemistry. Academic Press. p. 468. ISBN 978-0-12-352651-9. Retrieved 24 May 2023.
- ^ Ellern, Arkady; Boatz, Jerry A.; Christe, Karl O.; Drews, Thomas; Seppelt, Konrad (September 2002). "The Crystal Structures of ClF3O, BrF3O, and [NO]+[BrF4O]−". Zeitschrift für Anorganische und Allgemeine Chemie (in German). 628 (9–10): 1991–1999. doi:10.1002/1521-3749(200209)628:9/10<1991::AID-ZAAC1991>3.0.CO;2-1. ISSN 0044-2313. S2CID 94064764.
- ^ Haynes, William M. (9 June 2015). CRC Handbook of Chemistry and Physics, 96th Edition. CRC Press. pp. 4–53. ISBN 978-1-4822-6097-7. Retrieved 24 May 2023.
Fluorine compounds
Salts and covalent derivatives of the
fluoride
ion
HF ?HeF2 LiF BeF2 BF
BF3
B2F4
+BO3 CF4
CxFy
+CO3 NF3
FN3
N2F2
NF
N2F4
NF2
?NF5
+N
+NO3 OF2
O2F2
OF
O3F2
O4F2
?OF4 F2 Ne NaF MgF2 AlF
AlF3 SiF4 P2F4
PF3
PF5
+PO4 S2F2
SF2
S2F4
SF3
SF4
S2F10
SF6
+SO4 ClF
ClF3
ClF5 ?ArF2
?ArF4 KF CaF
CaF2 ScF3 TiF2
TiF3
TiF4 VF2
VF3
VF4
VF5 CrF2
CrF3
CrF4
CrF5
?CrF6 MnF2
MnF3
MnF4
?MnF5 FeF2
FeF3
FeF4 CoF2
CoF3
CoF4 NiF2
NiF3
NiF4 CuF
CuF2
?CuF3 ZnF2 GaF2
GaF3 GeF2
GeF4 AsF3
AsF5 Se2F2
SeF4
SeF6
+SeO3 BrF
BrF3
BrF5 KrF2
?KrF4
?KrF6 RbF SrF
SrF2 YF3 ZrF2
ZrF3
ZrF4 NbF4
NbF5 MoF4
MoF5
MoF6 TcF4
TcF
5
TcF6 RuF3
RuF
4
RuF5
RuF6 RhF3
RhF4
RhF5
RhF6 PdF2
Pd[PdF6]
PdF4
?PdF6 Ag2F
AgF
AgF2
AgF3 CdF2 InF
InF3 SnF2
SnF4 SbF3
SbF5 TeF4
?Te2F10
TeF6
+TeO3 IF
IF3
IF5
IF7
+IO3 XeF2
XeF4
XeF6
?XeF8 CsF BaF2 LuF3 HfF4 TaF5 WF4
WF5
WF6 ReF4
ReF5
ReF6
ReF7 OsF4
OsF5
OsF6
?OsF
7
?OsF
8 IrF2
IrF3
IrF4
IrF5
IrF6 PtF2
Pt[PtF6]
PtF4
PtF5
PtF6 AuF
AuF3
Au2F10
?AuF6
AuF5•F2 Hg2F2
HgF2
?HgF4 TlF
TlF3 PbF2
PbF4 BiF3
BiF5 ?PoF2
PoF4
PoF6 AtF
?AtF3
?AtF5 RnF2
?RnF
4
?RnF
6 FrF RaF2 LrF3 Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og ↓ LaF3 CeF3
CeF4 PrF3
PrF4 NdF2
NdF3
NdF4 PmF3 SmF
SmF2
SmF3 EuF2
EuF3 GdF3 TbF3
TbF4 DyF2
DyF3
DyF4 HoF3 ErF3 TmF2
TmF3 YbF2
YbF3 AcF3 ThF2
ThF3
ThF4 PaF4
PaF5 UF3
UF4
UF5
UF6 NpF3
NpF4
NpF5
NpF6 PuF3
PuF4
PuF5
PuF6 AmF2
AmF3
AmF4
?AmF6 CmF3
CmF4
?CmF6 BkF3
BkF
4 CfF3
CfF4 EsF3
EsF4
?EsF6 Fm Md No PF−6, AsF−6, SbF−6 compounds
AlF2−5, AlF3−6 compounds
chlorides, bromides, iodides
and pseudohalogenides
SiF2−6, GeF2−6 compounds
Oxyfluorides
Organofluorides
with transition metal,
lanthanide, actinide, ammonium
nitric acids
bifluorides
thionyl, phosphoryl,
and iodosyl
Chemical formulas
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