Atmospheric measurements of O2/N2 and CO2 at up to nine sites have been used to infer the interannual variations in oceanic O2 exchange with an inverse method. The method distinguishes the regional contributions of three latitudinal bands, partly the individual contributions of the North Pacific and the North Atlantic also. The interannual variations of the inferred O2 fluxes in the tropical band correlate significantly with the El Ni˜no/Southern Oscillation. Tropical O2 variations appear to be dominated by the ventilation of the O2 minimum zone from variations in Pacific equatorial upwelling. The interannual variations of the northern and southern extratropical bands are of similar amplitude, though the attribution to mechanisms is less clear. The interannual variations estimated by the inverse method are larger than those estimated by the current generation of global ocean biogeochemistry models, especially in the North Atlantic, suggesting that the representation of biological processes plays a role. The comparison further suggests that O2 variability is a more stringent test to validate models than CO2 variability, because the processes driving O2 variability combine in the same direction and amplify the underlying climatic signal
Submitted on Dec 21, 2007
Accepted on Aug 11, 2008
Published on Jan 1, 2008
ReferencesBaker , D. F. , Law , R. M. , Gurney , K. R. , Rayner , P. , Peylin , P. and co-authors . 2006 . Transcom 3 inversion intercomparison: Impact of transport model errors on the interannual variability of regional co2 fluxes, 1988-2003. Global Biogeochem. Cycles 20 , GB1002, https://doi.org/10.1029/2004GB002439 .
Battle , M. , Milcaloff Fletcher , S. , Bender , M. , Keeling , R. , Manning , A. and co-authors . 2006 . Atmospheric potential oxygen: New observa-tions and their implications for some atmospheric and oceanic models. Global Biogeochem. Cycles 20 , GB1010.
Behrenfeld , M. J. , O'Malley , R. T. , Siegel , D. A. , McClain , C. R. , Sarmiento , J. L. and co-authors . 2006 . Climate-driven trends in con-temporary ocean productivity. Nature 444 , 752 - 755 .
Bender , M. L. , Tans , P. P. , Ellis , J. T. , Orchardo , J. and Habfast , K . 1994 . A high precision isotope ratio mass spectrometry method for measuring the 02/N2 ratio of air. Geochim. Cosmochim. Acta 58 , 4751 – 4758 .
Bender , M. L. , Ho , D. T. , Hendricks , M. B. , Mika , R. , Battle , M. 0. and co-authors. 2005 . Atmospheric 02/N2 changes, 1993-2002: Im-plications for the partitioning of fossil-fuel CO2 sequestration. Global Biogeochem. Cycles 19 , GB4017, https://doi.org/10.1029/2004GB002410 .
Bousquet , R , Peylin , R , Ciais , P. , Le Quere , C. , Friedlingstein , P. and co-authors . 2000 . Regional changes in carbon dioxide fluxes of land and oceans since 1980. Science 290 , 1342 - 1346 .
Ebisuzalci , W . 1997 . A method to estimate the statistical significance of a correlation when the data are serially correlated. J. Clim . 10 , 2147 – 2153 .
Feely , R. , Boutin , J. , Cosca , C. , Dandonneau , Y. , Etcheto , J. and co-authors . 2002 . Seasonal and interannual variability of CO2 in the equatorial Pacific
Feely , R. A. , Takahashi , T. , Wanninkhof , R. , McPhaden , M. J. , Cosca , C. E. and co-authors . 2006 . Decadal variability of the air—sea co2 fluxes in the equatorial pacific ocean. J. Geophys. Res . 111 , C08590. Deep Sea Res. 49 , 2443 - 2469 .
Fichefet , T. and Maqueda , M. A. M . 1999 . Modelling the influence of snow accumulation and snow-ice formation on the seasonal cycle of the Antarctic sea-ice cover. Clim. Dyn . 15 , 251 – 268 .
Garcia , H. E. and Keeling , R. E 2001 . On the global oxygen anomaly and air-sea flux. J. Geophys. Res . 106 , 31155 – 31166 .
Gaspar , P. , Gregoris , Y. and Lefevre , J. M . 1990 . A simple eddy kinetic energy model for simulations of the oceanic vertical mixing: tests at station Papa and Long-Term Upper Ocean Study Site site. J. Geophys. Res . 95 , 16 179 - 16 193 .
Gent , P. R. and McWilliams , J. C . 1990 . Isopycnal mixing in ocean circulation models. J. Phys. Oceanogr 20 , 150 – 155 .
Gloor , M. , Gruber , N. , Sarmiento , J. , Sabine , C. L. , Feely , R. A. and co-authors . 2003 . A first estimate of present and preindustrial air-sea CO2 flux patterns based on ocean interior carbon measurements and models. Geophys. Res. Lett . 30 , 1010, https://doi.org/10.1029/2002GL015594 .
Gruber , N. , Gloor , M. , Fan , S.-M. and Sarmiento , J. L . 2001 . Air-sea flux of oxygen estimated from bulk data: Implications for the marine and atmospheric oxygen cycles. Global Biogeochem. Cycles 15, 783 – 803 .
Gurney , K. R. , Law , R. M. , Denning , A. S. , Rayner , P. J. , Baker , D. and co-authors . 2002 . Towards robust regional estimates of CO2 sources and sinks using atmospheric transport models. Nature 415 , 626 - 630 .
Hamme , R. and Keeling , R. F . 2008 . Ocean ventilation as a driver of interannual variability in atmospheric potential oxygen. Tellus 60B , https://doi.org/10.1111/j.1600-0889.2008.00376.x .
Hansen , P . 1998 , Rank-Deficient and Discrete III-Posed Problems . Nu-merical Aspects of Linear Inversion, Society for Industrial and Ap-plied Mathematics , Philadelphia , USA .
Heimann , M. and Körner , S . 2003 . The global atmospheric tracer model TM3, Technical Report 5, Max Planck Institute for Biogeochemistry, Jena, Germany.
Kalnay , E. , Kanamitsu , M. , Kistler , R. , Collins , W. , Deaven , D. and co-authors . 1996 . The NCEP/NCAR 40-year reanalysis project. Bull. Am. Met. Soc . 77 , 437 - 471 .
Keeling , R. E 1988 . Development of an Interferometric Oxygen Analyzer for Precise Measurement of the Aimospheric 02 mole Fraction, Ph . D. thesis, Harvard Univ., Cambridge , USA .
Keeling , R. F. and Shertz , S. R . 1992 . Seasonal and interannual variations in atmospheric oxygen and implications for the global carbon cycle. Nature 358 , 723 – 727 .
Keeling , R. F. , Najjar , R. P. , Bender , M. L. and Tans , P. P. 1993 . What atmospheric oxygen measurements can tell us about the global carbon-cycle. Global Biogeochem. Cycles pp. 37-67.
Keeling , R. F. and Severinghaus , J. P . 2000 . Atmospheric oxygen and the carbon cycle . In: The Carbon Cycle Volume 6: (eds T . M. L., Wigley and D. S., Schimel), Global Change Institute : Cambridge, Cambridge University Press , pp. 134 – 140 .
Keeling , R. F. , Manning , A. C. , Paplawsky , W. J. and Cox , A. C . 2007 . On the long-term stability of reference gases for atmospheric 02/N2 and CO2 measurements. Tellus 59B , 3 – 14 .
Langenfelds , R. , Francey , R. J. , Steele , L. P. , Battle , M. , Keeling , R. F. and co-authors . 1999 . Partitioning of the global fossil CO2 sink using a 19-year trend in atmospheric 02. Geophys. Res. Lett . 26 , 1897– 1900 .
Laws , E. A. , Falkowski , P. G. , Smith W. 0. Jr. , Ducklow , H . and Mc-Carthy , J. J. 2000 . Temperature effects on export production in the open ocean. Global Biogeochemical Cycles 14 , 1231 - 1246 .
Le Quere , C. , Harrison , S. P. , Prentice , I. C. , Buitenhuis , E. T. , Aumont , O. and co-authors. 2005 . Ecosystem dynamics based on plankton functional types for global ocean biogeochemistry models. Global Biogeochem. Cycles 11 , 2016 - 2040 .
Le Quere , C. , Rödenbeck , C. , Buitenhuis , E. T. , Conway , T. J. , Langen-felds , R. and co-authors . 2007 . Saturation of the Southern ocean CO2 sink due to recent climate change. Science 316 , 1735-1738. Manning , A. C. and Keeling , R. E 2006. Global oceanic and land biotic carbon sinks from the scripps atmospheric oxygen flask sampling network. Tellus 58B , 95 - 116 .
McKinley , G. A. , Follows , M. J. and Marshall , J . 2000 . Interannual variability of the air-sea flux of oxygen in the north Atlantic. Geophys. Res. Lett . 27 , 2933 – 2936 .
McKinley , G. A. , Takahashi , T. , Buitenhuis , E. , Chai , E , Christian , J. and co-authors . 2006 . North Pacific carbon cycle response to climate variability on seasonal to decadal timescales. J. Geophys. Res . 111 , https://doi.org/10.1029/2005JC003173 .
Najjar , R. G. and Keeling , R. F . 2000 . Mean annual cycle of the air-sea oxygen flux: a global view. Global Biogeochemical Cycles 14 , 573 – 584 .
Nagler , T. , Ciais , P. , On , J. , Aumont , 0. and Rödenbeck , C. 2007 . On evaluating ocean models with atmospheric potential oxygen. Tellus 59B , 138 - 156 .
Olivier , J. G. J. and Berdowski , J. J. M . 2001 . Global emissions sources and sinks. In: The Climate System (eds. J. Berdowski , R . Guicherit and B. J. Heij , A. A. Balkema Publishers/Swets & Zeitlinger Publishers, Lisse, The Netherlands, 33-78, ISBN 90 5809 255 0.
Peylin , P. , Bousquet , P. , Le Quere , C. , Sitch , S. , Friedlingstein , P. , and co-authors . 2005 . Multiple constraints on regional CO2 flux variations over land and oceans. Global Biogeochem. Cycles 19 , https://doi.org/10.1029/2003GB002214 .
Rayner , P. , Enting , I. , Francey , R . and Langenfelds , R . 1999. Recon-structing the recent carbon cycle from atmospheric CO2, 313 CO2 and 02/N2 observations. Tellus 51B , 213 - 232 .
Rödenbeck , C. , Houweling , S. , Gloor , M. and Heimann , M . 2003 . CO2 flux history 1982-2001 inferred from atmospheric data using a global inversion of atmospheric transport. Atmos. Chem. Phys . 3 , 1919 – 1964 .
Rödenbeck , C . 2005 . Estimating CO2 sources and sinks from atmo-spheric mixing ratio measurements using a global inversion of at-mospheric transport, Technical Report 6, Max Planck Institute for Biogeochemistry, Jena, Germany.
Schuster , U. and Watson , A. J . 2007 . A variable and decreasing sink for atmospheric CO2 in the North Atlantic. J. Geophys. Res . 112 , https://doi.org/10.1029/2006JC003941 .
Severinghaus , J. P . 1995 . Studies of the Terrestrial 02 and Carbon Cycles in Sand due to Cases and in Biosphere 2, Ph . D. thesis, Columbia Univ., New York , USA .
Stephens , B. B. , Keeling , R. F. , Heimann , M. , Six , K. D. , Murnane , R . and co-authors. 1998 . Testing global ocean carbon cycle models using measurements of atmospheric 02 and CO2 concentration. Global Biogeochem. Cycles 12 , 213 - 230 .
Stephens , B. B. , Bakwin , P . S., Tans , P . P., Teclaw , R . M. and Baumann , D. D. 2007 . Application of a differential fuel-cell analyzer for mea-suring atmospheric oxygen variations. J. Atmos. Ocean. Technol . 24 , 82 - 94 .
Takahashi , T. , Sutherland , S. C. , Sweeney , C. , Poisson , A. and co-authors . 2002 . Global sea-air CO2 flux based on climatological surface ocean pCO2, and seasonal biological and temperature effects. Deep Sea Res. 11 49 , 1601 - 1623 .
Tohjima , Y. , Mulcai , H ., Machida , T . and Nojiri , Y . 2003 . Gas-chromatographic measurements of the atmospheric oxygen/nitrogen ratio at hateruma island and cape ochi-ishi, japan. Geophys. Res. Lett . 30 , 1653, https://doi.org/10.1029/2003GL017282 .
Tohjima , Y. , Mukai , H ., Machida , T. , Nojiri , Y . and Gloor , M . 2005 . First measurements of the latitudinal atmospheric 02 and CO2 distributions across the western pacific. Geophys. Res. Lett . 32 , L17805.
Weiss , R. F . 1970 . The solubility of nitrogen, oxygen and argon in water and seawater. Deep-Sea Res . 17 , 721 – 735 .
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