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Showing content from http://www.buffingtonfx.com/j1432/animatronics/molds.html below:

Molds and materials

This, by far is the area that I did the majority of my learning for this project. There are many materials that can be used for animatronics. I have barely scratched the surface of what is out there, but I hope that his page can get you going . I am going to divide it up into sections since I have a bit to say about each. Something that applies to all of them is that you should not expect to get a decent mold done in any less than a day. I imagine that when you get a lot more experienced, you will be able to.
Something that is a good idea for all of the pourable molds is that you must try to build up clay around your model to the point where it is the the widest across. This will help get rid of undercuts and allow you to extract your object easier. Extend the clay at least an inch away from the object to allow for a good match up with your other parts. It is not a bad idea to make 'keys' in your molds to facilitate putting them back together when you cast. A good example of a key would be pressing a marble halfway into the clay and then pulling it out.
One final thing that you can do tha save money or to facilitate removal of a mold that has a lot of undercuts (flexible molds) is to make a thin coat of the mold material getting rid of any undercuts then use plaster or some other strong material such as fiberglass resin to make a 'mother mold' which will help the flexible mold keep its shape.

Choose from the following or just scroll downLatex


Silicone
Polyurethane
Plaster
Back to Animatronics page
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Latex

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Silicone

Silicone RTV This stuff is great! This is really only a molding material, but it is easy to use. RTV costs a lot, so when you use it, it is usually a good idea to get creative and do your best to keep the volume that you use of it down. RTV can deal with some pretty severe undercuts without problems. Nothing sticks to it except for more silicone, so you never need a mold release. You can actually do a one part mold of something such as a small bust with this stuff. Just make sure that you can get a good grip on it when you pull it out. One part molds are common with this stuff. Some varieties of silicone RTV can actually have some softer metals cast in them. When pouring RTV, which by the way stands for Room Temperature Vulcanizing, you should put it in a cup or some other type of container then poke a hole on the bottom edge. Put your item to be molded under it a couple of feet. When the silicone flows out, it will then become a very fine string, and any bubbles that were in it pop. If you have a budget, the you can put the mixed silicone in a vacuum chamber to pop all of the bubbles before you pour. When pouring, do not pour directly on top of the object, rather pour beside it, and let the silicone gradually flow over it. Silicone will pick up the finest of details. I understand that doctors sometimes use it to get impressions of individual cells! Make sure to mix this well. Any streaks that are not fully mixed will not cure. In an effort to minimize the silicone usage, you can do an impression coat of silicone and then after that dries, a thicker coat of silicone mixed with cab-o-sil. You can thicken any non water-based mixture with cab-o-sil. Make sure to wear a respirator since the individual particles of this stuff are the same size of cigarette smoke.

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Polyurethane

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Plaster

Plaster is really hard to use, but it is the only thing that you can do foam latex with since it is porous. With plaster, make sure that you have no undercuts. If you do not, you will have a heck of a time getting your origional out of the plaster. Plaster does not stick to plaster. If you don't quite have enough plaster mixed to finish a pour, hurry up and mix a new batch. When you pour in this batch, try to mix it some with the already poured plaster. Cold water slows down the cure time. There are different types of plaster, but the differences are not all that great. I have used Pottery plaster and Ultracal. Pottery plaster is a white plaster that is fairly easy to break . Ultracal is the recommended type to use for foam latex because it hold up to heat pretty well. Ultracal is extremely hard. Make sure that you have your origional does not float up into this stuff. I had that happen, and I spent the better part of an hour chiseling away with a cold chisel and a mallet to free my origional. You want to let your molds cool as slowly as you can if you have baked them because they will spontaneously crack after repeated baking sessions. You might want to try soaking them in water a little before you use them again to do some more foam latex.


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