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Showing content from http://sitem.herts.ac.uk/aeru/ppdb/en/Reports/1062.htm below:

Glyphosate-trimesium

Data alerts

The following alerts are based on the data in the tables below. An absence of an alert does not imply the substance has no implications for human health, biodiversity or the environment but just that we do not have the data to form a judgement.

A herbicide used in a wide range of cropping, utility and industrial situations for broad-spectrum control of weeds and grases Annual and perennial weeds, Broadleaved weeds, Grasses Cereals; Soybeans; Glyphosate tolerant crops; Horticulture; Forestry; Domestic gardens, lawns Efficacy demonstrated by field trials and extensive global use Current 1971, first reported; 1989, introduced in Spain Approved 15/12/2026 Check label - may vary with formulation EC Regulation 1107/2009 (repealing 91/414) Approved Assessment Group on Glyphosate 15/12/2033 No Yes

ATAustria

BEBelgium

BGBulgaria

CYCyprus

CZCzech Republic

DEGermany

DKDenmark

EEEstonia

ELGreece

✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓

ESSpain

FIFinland

FRFrance

HRCroatia

HUHungary

IEIreland

ITItaly

LTLithuania

LULuxembourg

✓ ✓ ✓ ✓ ✓ ✓ ✓

LVLatvia

MTMalta

NLNetherlands

PLPoland

PTPortugal

RORomania

SESweden

SISlovenia

SKSlovakia

✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓

ISIceland

NONorway

✓ Chemical structure None C₆H₁₆NO₅PS C[S+](C)C.C(C(=O)O)NCP(=O)(O)[O-] Not applicable RUCAXVJJQQJZGU-UHFFFAOYSA-M InChI=1S/C3H8NO5P.C3H9S/c5-3(6)1-4-2-10(7,8)9;1-4(2)3/h4H,1-2H2,(H,5,6)(H2,7,8,9);1-3H3/q;+1/p-1 Yes Cambridge Crystallographic Data Centre diagrams General status Herbicide Organophosphate herbicide; Phosphonoglycine herbicide 950 g kg⁻¹ as acid EU dossier - None declared Synthetic Broad-spectrum, systemic, translocated and non-residual. Inhibition of EPSP synthase. 81591-81-3 213-997-4 284 128501 105048 607-315-00-8 245.23 trimethylsulfonium N-[(hydroxyphosphinato)methyl]glycine trimethylsulfonium N-[(hydroxyphosphinato)methyl]glycine 2-(phosphonomethylamino)acetate; trimethylsulfonium Risk of herbicide resistance developing - anti-resistance management required; PAN listed Highly Hazardous Chemical - G 9 Not applicable Not applicable Eleusine indica, Euphorbia heterophylla White solid

glyphosate

glyphosate-diammonium

glyphosate-monoammonium

glyphosate-monopotassium

Monsanto
Syngenta

Coloso
Ouragan
Zapp

Often supplied as a soluble concentrate that is mixed with water and applied as a spray 1050000

Q3 Q = Miscellaneous data from online sources 3 = Unverified data of known source

Non-persistent 29

A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes - - - - EU 2015 dossier lab studies DT₅₀ range 3-62 days, DT₉₀ range 81-207 days, field studies DT₅₀ range 1.5-34 days USA and Germany, DT₉₀ range 76-326 days - - - - - - - - 81

A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes Slow - - - As this parameter is not normally measured directly, a surrogate measure is used: ‘Photochemical oxidative DT₅₀’. Where data is available, this can be found in the Fate Indices section below. - Soil adsorption and mobility - - - - - 0.93

A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes Non-mobile 27621 0.97 EU 2015 dossier K_foc 530-180000 mL g⁻¹, ¹/_n range 0.84-1.1 No -0.59 Calculated Low leachability 5.35 X 10^-03 Calculated - Estimated concentrations of chemicals with Koc values greater than 9995 ml g⁻¹ are beyond the scope of the regression data used in SCI-GROW development. If there are concerns for such chemicals, a higher tier groundwater exposure assessment should be considered, regardless of the concentration returned by SCI-GROW Medium Calculated - Non-mobile Calculated - - - - Low risk

A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes Based on LogP < 3 Low risk - - Known soil metabolites Major fraction 1.0 - Major fraction 0.154 - Known groundwater metabolites Relevant - - Relevant - - Other known metabolites

None

Terrestrial ecotoxicology 748

A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 4 = Verified data Eisenia foetida as glyphosate Moderate Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect

F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents / FAO data, IPCS INCHEM data (US EPA Databases Related to Pesticide Risk Assessment ) 3 = Unverified data of known source Americamysis bahia Moderate - - - - - - - - - 12

F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents / FAO data, IPCS INCHEM data (US EPA Databases Related to Pesticide Risk Assessment ) 4 = Verified data Crassostrea gigas Embryo - HUMAN HEALTH AND PROTECTION High (class III) - - 748

A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes - - - - Risks to bystanders and residents considered low PPE/PPC recommended to reduce risks EU MRL pesticide database GB MRL Register GB MRL amended July 2021 - - - - - - Rapid and extensive - approx 90% in 24hrs mainly via faeces

?Possibly, status not identified

A0 A = Chromosome aberration (EFSA database) 0 = No data

;

B0 B = DNA damage/repair (EFSA database) 0 = No data

;

C0 C = Gene mutation (EFSA database) 0 = No data

;

D0 D = Genome mutation (EFSA database) 0 = No data

;

E3 E = Unspecified genotoxicity type (miscellaneous data source) 3 = Negative

No data found Reproduction / development effects Acetyl cholinesterase inhibitor Neurotoxicant

?Possibly, status not identified

XNo, known not to cause a problem

Respiratory tract irritant Skin irritant Skin sensitiser

XNo, known not to cause a problem

✓Yes, known to cause a problem

XNo, known not to cause a problem

Eye irritant Phototoxicant

✓Yes, known to cause a problem

No data found IARC Group 2A carcinogen; US EPA - no evidence to support classification as human carcinogen; EFSA - inconclusive data for cancer in humans
Possible bladder and liver toxicant IMDG Transport Hazard Class 9
Not expected to auto-ignite; Not highly flammable
Not oxidising or explosive Health: H302
Environment: H411 III (Slightly hazardous) UN3077 Packaging Group III (minor danger) - glyphosate-trimesium - - - - - - glifosat-trimesium - - - - Record last updated: 11/04/2025 Contact: aeru@herts.ac.uk Please cite as: Lewis, K.A., Tzilivakis, J., Warner, D. and Green, A. (2016) An international database for pesticide risk assessments and management. Human and Ecological Risk Assessment: An International Journal, 22(4), 1050-1064. DOI: 10.1080/10807039.2015.1133242

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